[Group A] [Group B] [Group C] [Group D] [Group E] [Group F] [Group G] [Group H]
| Day | Date | Team 1 | Team 2 | Score |
| 1 | 2022-09-07 | Ajax | Rangers | 4-0 |
| 1 | 2022-09-07 | Napoli | Liverpool | 4-1 |
| 2 | 2022-09-13 | Liverpool | Ajax | 2-1 |
| 2 | 2022-09-14 | Rangers | Napoli | 0-3 |
| 3 | 2022-10-04 | Liverpool | Rangers | 2-0 |
| 3 | 2022-10-04 | Ajax | Napoli | 1-6 |
| 4 | 2022-10-12 | Napoli | Ajax | 4-2 |
| 4 | 2022-10-12 | Rangers | Liverpool | 1-7 |
| 5 | 2022-10-26 | Napoli | Rangers | 3-0 |
| 5 | 2022-10-26 | Ajax | Liverpool | 0-3 |
| 6 | 2022-11-01 | Liverpool | Napoli | 2-0 |
| 6 | 2022-11-01 | Rangers | Ajax | 1-3 |
| Team: | Matches | Wins | Draws | Losses | G-R | Points | |
| Napoli | 6 | 5 | 0 | 1 | 20 | 6 | 15 |
| Liverpool | 6 | 5 | 0 | 1 | 17 | 6 | 15 |
| Ajax | 6 | 2 | 0 | 4 | 11 | 16 | 6 |
| Rangers | 6 | 0 | 0 | 6 | 2 | 22 | 0 |
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