[Group A] [Group B] [Group C] [Group D] [Group E] [Group F] [Group G] [Group H]
| Day | Date | Team 1 | Team 2 | Score |
| 1 | 2005-09-14 | Villarreal | Man. United | 0-0 |
| 1 | 2005-09-14 | Benfica | Lille | 1-0 |
| 2 | 2005-09-27 | Lille | Villarreal | 0-0 |
| 2 | 2005-09-27 | Man. United | Benfica | 2-1 |
| 3 | 2005-10-18 | Man. United | Lille | 0-0 |
| 3 | 2005-10-18 | Villarreal | Benfica | 1-1 |
| 4 | 2005-11-02 | Lille | Man. United | 1-0 |
| 4 | 2005-11-02 | Benfica | Villarreal | 0-1 |
| 5 | 2005-11-22 | Man. United | Villarreal | 0-0 |
| 5 | 2005-11-22 | Lille | Benfica | 0-0 |
| 6 | 2005-12-07 | Villarreal | Lille | 1-0 |
| 6 | 2005-12-07 | Benfica | Man. United | 2-1 |
| Team: | Matches | Wins | Draws | Losses | G-R | Points | |
| Villarreal | 6 | 2 | 4 | 0 | 3 | 1 | 10 |
| Benfica | 6 | 2 | 2 | 2 | 5 | 5 | 8 |
| Man. United | 6 | 1 | 3 | 2 | 3 | 4 | 6 |
| Lille | 6 | 1 | 3 | 2 | 1 | 2 | 6 |
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